1258276-28-6
- Product Name：(S)-12-hydroxy-1,10-bis(2,4,6-triisopropylphenyl)-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide
- Molecular Formula：C47H59O4P
- Purity：99%
- Molecular Weight：718.957
Product Details
Purity:99%
Offer Buy Quality (S)-12-hydroxy-1,10-bis(2,4,6-triisopropylphenyl)-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide 1258276-28-6 Cheapest Price
- Molecular Formula:C47H59O4P
- Molecular Weight:718.957
- Boiling Point:749.7±70.0 °C(Predicted)
- PKA:1.15±0.20(Predicted)
- PSA：65.57000
- Density:1.16±0.1 g/cm3 (20 oC 760 Torr)
- LogP:13.81110
1258276-28-6 Relevant articles
Asymmetric allylboration of aldehydes with pinacol allylboronates catalyzed by 1,1′-spirobiindane-7,7′-diol (SPINOL) based phosphoric acids
Xing, Chun-Hui,Liao, Yuan-Xi,Zhang, Yimei,Sabarova, Darya,Bassous, Monica,Hu, Qiao-Sheng
supporting information; experimental part, p. 1115 - 1118 (2012/04/10)
The asymmetric allylboration of aldehyde...
1258276-28-6 Process route
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1258276-31-1,1372719-98-6
(R)-6,6'-bis(2,4,6-triisopropylphenyl)-1,1'-spirobiindane-7,7'-diol
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1258276-28-6,1372719-95-3
(R)-6,6'-bis(2,4,6-triisopropylphenyl)-1,1'-spirobiindanyl-7,7'-diyl hydrogen phosphate
| Conditions | Yield |
|---|---|
|
(R)-6,6'-bis(2,4,6-triisopropylphenyl)-1,1'-spirobiindane-7,7'-diol;
With
pyridine; trichlorophosphate;
at 100 ℃;
Inert atmosphere;
With
hydrogenchloride; water;
In
1,2-dichloro-ethane; N,N-dimethyl-formamide;
at 100 ℃;
for 3h;
|
76% |
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1258276-29-7,930784-50-2
(R)-6,6'-diiodo-7,7'-bis(methoxymethoxy)-2,2',3,3'-tetrahydro-1,1'-spirobiindane
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1258276-28-6,1372719-95-3
(R)-6,6'-bis(2,4,6-triisopropylphenyl)-1,1'-spirobiindanyl-7,7'-diyl hydrogen phosphate
| Conditions | Yield |
|---|---|
|
Multi-step reaction with 3 steps
1.1: magnesium
1.2: 16 h / 70 °C / Inert atmosphere
2.1: hydrogenchloride / methanol; chloroform; water / 18 h / 70 °C
3.1: pyridine; trichlorophosphate / 100 °C / Inert atmosphere
3.2: 3 h / 100 °C
With
pyridine; hydrogenchloride; magnesium; trichlorophosphate;
In
methanol; chloroform; water;
|
1258276-28-6 Upstream products
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1258276-31-1
(R)-6,6'-bis(2,4,6-triisopropylphenyl)-1,1'-spirobiindane-7,7'-diol
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1258276-29-7
(R)-6,6'-diiodo-7,7'-bis(methoxymethoxy)-2,2',3,3'-tetrahydro-1,1'-spirobiindane
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21524-34-5
2,4,6-triisopropyl-1-bromobenzene
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