1412439-82-7
- Product Name：(11aS)-3,7-Bis(3,5-dimethylphenyl)-10,11,12,13-tetrahydro-5-hydroxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-oxide
- Molecular Formula：
- Purity：99%
- Molecular Weight：522.581
Product Details
Purity:99%
Top Purity 99% Buy Reliable Quality (11aS)-3,7-Bis(3,5-dimethylphenyl)-10,11,12,13-tetrahydro-5-hydroxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-oxide 1412439-82-7 On Stock
- Molecular Formula:C33H31O4P
- Molecular Weight:522.581
1412439-82-7 Relevant articles
Optically active 1,1′-Spirobiindane-7,7′-diol (SPINOL)-based phosphoric acids as highly enantioselective catalysts for asymmetric organocatalysis
Xing, Chun-Hui,Liao, Yuan-Xi,Ng, Jaclynn,Hu, Qiao-Sheng
, p. 4125 - 4131 (2011/07/07)
The synthesis and application of a serie...
Asymmetric Ni-H insertion reaction cooperatively catalyzed by rhodium and chiral spiro phosphoric acids
Xu, Bin,Zhu, Shou-Fei,Xie, Xiu-Lan,Shen, Jun-Jie,Zhou, Qi-Lin
supporting information; experimental part, p. 11483 - 11486 (2012/01/11)
So near so SPA: Achiral dirhodium(II) ca...
1412439-82-7 Process route
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930784-56-8
(R)-6,6'-di(3,5-dimethylphenyl)-1,1'-spirobiindane-7,7'-diol
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1297613-75-2,1412439-82-7
C33H31O4P
Conditions
| Conditions | Yield |
|---|---|
|
Multi-step reaction with 2 steps
1: pyridine; trichlorophosphate / Inert atmosphere
2: hydrogenchloride; water; acetic acid / 1,2-dichloro-ethane / Reflux
With
pyridine; hydrogenchloride; water; acetic acid; trichlorophosphate;
In
1,2-dichloro-ethane;
|
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![(R)-6,6'-dibromo-2,2',3,3'-tetrahydro-1,1'-spirobis[1H-indole]-7,7'-diphenol](/upload/2024/4/ea608513-9b92-49aa-a305-c6408fb67605.png)
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1621066-74-7,1807777-59-8
(R)-6,6'-dibromo-2,2',3,3'-tetrahydro-1,1'-spirobis[1H-indole]-7,7'-diphenol
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-
1297613-75-2,1412439-82-7
C33H31O4P
Conditions
| Conditions | Yield |
|---|---|
|
Multi-step reaction with 3 steps
1: tris-(dibenzylideneacetone)dipalladium(0); potassium phosphate / 1,4-dioxane; toluene / 105 - 110 °C / Inert atmosphere
2: pyridine; trichlorophosphate / Inert atmosphere
3: hydrogenchloride; water; acetic acid / 1,2-dichloro-ethane / Reflux
With
pyridine; hydrogenchloride; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); water; acetic acid; trichlorophosphate;
In
1,4-dioxane; 1,2-dichloro-ethane; toluene;
|
1412439-82-7 Upstream products
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930784-56-8
(R)-6,6'-di(3,5-dimethylphenyl)-1,1'-spirobiindane-7,7'-diol
-
1621066-74-7
(R)-6,6'-dibromo-2,2',3,3'-tetrahydro-1,1'-spirobis[1H-indole]-7,7'-diphenol
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