1297613-72-9
- Product Name：(11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-diphenyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-oxide
- Molecular Formula：C29H23O4P
- Purity：99%
- Molecular Weight：466.46
Product Details
pd_meltingpoint:>300℃
Purity:99%
Best Quality Buy Reliable Quality (11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-diphenyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-oxide 1297613-72-9 Cheap Price
- Molecular Formula:C29H23O4P
- Molecular Weight:466.46
- Melting Point:>300℃
- Boiling Point:661.7±65.0 °C(Predicted)
- PKA:1.14±0.20(Predicted)
- Density:1.42
1297613-72-9 Relevant articles
Optically active 1,1′-Spirobiindane-7,7′-diol (SPINOL)-based phosphoric acids as highly enantioselective catalysts for asymmetric organocatalysis
Xing, Chun-Hui,Liao, Yuan-Xi,Ng, Jaclynn,Hu, Qiao-Sheng
, p. 4125 - 4131 (2011/07/07)
The synthesis and application of a serie...
Asymmetric Ni-H insertion reaction cooperatively catalyzed by rhodium and chiral spiro phosphoric acids
Xu, Bin,Zhu, Shou-Fei,Xie, Xiu-Lan,Shen, Jun-Jie,Zhou, Qi-Lin
supporting information; experimental part, p. 11483 - 11486 (2012/01/11)
So near so SPA: Achiral dirhodium(II) ca...
SPINOL-derived phosphoric acids: Synthesis and application in enantioselective Friedel-Crafts reaction of indoles with imines
Xu, Fangxi,Huang, Dan,Han, Chao,Shen, Wei,Lin, Xufeng,Wang, Yanguang
supporting information; experimental part, p. 8677 - 8680 (2011/02/26)
A new class of chiral phosphoric acids w...
1297613-72-9 Process route
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930784-55-7,1258326-98-5
(S)-6,6'-diphenyl-1,1'-spirobiindane-7,7'-diol
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-
1297613-72-9
(S)-6,6'-diphenyl-1,1'-spirobiindane-7,7'-diyl phosphate
| Conditions | Yield |
|---|---|
|
(S)-6,6'-diphenyl-1,1'-spirobiindane-7,7'-diol;
With
pyridine; trichlorophosphate;
at 0 - 70 ℃;
for 3h;
Inert atmosphere;
With
water;
at 0 - 110 ℃;
for 4h;
Inert atmosphere;
|
88% |
-
-
C29H22ClO3P
-
-
1297613-72-9
(R)-6,6'-diphenyl-1,1'-spirobiindanyl-7,7'-diyl hydrogenphosphate
| Conditions | Yield |
|---|---|
|
With
hydrogenchloride; water; acetic acid;
In
1,2-dichloro-ethane;
Reflux;
|
|
|
With
water;
at 90 ℃;
for 12h;
|
1297613-72-9 Upstream products
-
930784-55-7
(S)-6,6'-diphenyl-1,1'-spirobiindane-7,7'-diol
-
98-80-6
phenylboronic acid
-
1621066-74-7
(R)-6,6'-dibromo-2,2',3,3'-tetrahydro-1,1'-spirobis[1H-indole]-7,7'-diphenol
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930784-55-7
(R)-6,6'-diphenyl-1,1'-spirobiindane-7,7'-diol
Relevant Products
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